%0 Journal Article %T A binuclear vanadium oxyfluoride: di-μ-oxido-bis[fluoridooxido(1,10-phenanthroline)vanadium(V)] %A Paul DeBurgomaster %A Jon Zubieta %J Acta Crystallographica Section E %D 2010 %I International Union of Crystallography %R 10.1107/s1600536810037232 %X The title compound, [V2F2O4(C12H8N2)2], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octahedral environment. The symmetry-equivalent VV atoms exhibit coordination geometries defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the phenanthroline ligands. The crystal packing is stabilized by weak intermolecular C¡ªH...O and C¡ªH...F hydrogen bonds. %U http://scripts.iucr.org/cgi-bin/paper?S1600536810037232