%0 Journal Article
%T (Ferrocenylthiophosphonato-κS)(triphenylphosphane-κP)gold(I) dichloromethane monosolvate
%A Hendriette van der Walt
%A Alfred Muller
%A Richard J. Staples
%A Werner E. Van Zyl
%J Acta Crystallographica Section E
%D 2010
%I International Union of Crystallography
%R 10.1107/s1600536810039255
%X In the title compound, [AuFe(C5H5)(C5H5O2PS)(C18H15P)]，CH2Cl2, the two-coordinate gold(I) atom shows a slightly distorted linear arrangement, with a P！Au！S bond angle of 176.81 (6)＜. The difference in P=O and P！O(H) bond lengths, which are 1.503 (6) and 1.541 (5)  , respectively, implies there is apparently no delocalization between the P！O bonds, and the proton appears to be localized on one O atom only. In the crystal structure, intermolecular O！H...O hydrogen bonds link dinuclear molecules into chains propagated in the [010] direction. The dichloromethane solvent molecule was disordered between two positions in a 0.63 (3):0.37 (3) ratio.
%U http://scripts.iucr.org/cgi-bin/paper?S1600536810039255