%0 Journal Article %T [2,6-Bis(p-tolyliminomethyl)pyridine-κ3N,N′,N′′]dichloridocopper(II) %A Xiao-Ping Li %A Jian-She Zhao %A Seik Weng Ng %J Acta Crystallographica Section E %D 2010 %I International Union of Crystallography %R 10.1107/s1600536810037025 %X The title compound, [CuCl2(C21H19N3)], lies on a twofold rotation axis that passes through the Npyridyl¡ªCu bond; this symmetry element relates one half of the organic ligand to the other as well as one Cl ligand to the other. The three N atoms span the axial¨Cequatorial¨Caxial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the CuII atom is 31% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). %U http://scripts.iucr.org/cgi-bin/paper?S1600536810037025