%0 Journal Article
%T [N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ2N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V)
%A Lin Liu
%J Acta Crystallographica Section E
%D 2011
%I International Union of Crystallography
%R 10.1107/s1600536811010385
%X In the title molecule, [V(C15H10I2N2O2)(CH3O)O(CH3OH)], the VV atom is coordinated by one N and two O atoms from an N¡ä-(3,5-diiodo-2-oxidobenzylidene-¦ÊO)-4-methylbenzohydrazidate (L) ligand, one oxide O atom, one methanolate [V¡ªO = 1.761 (3)  ] and one methanol [V¡ªO = 2.383 (4)  ] O atom in a distorted octahedral geometry. In the L ligand, the two benzene rings are nearly parallel, forming a dihedral angle of 2.0 (1)¡ã. In the crystal, intermolecular O¡ªH...N hydrogen bonds link pairs of molecules into centrosymmetric dimers which exhibit ¦Ð¨C¦Ð interactions between the aromatic rings [centroid¨Ccentroid distance = 3.677 (5)  ].
%U http://scripts.iucr.org/cgi-bin/paper?S1600536811010385