%0 Journal Article
%T Diazidobis(5,5′-dimethyl-2,2′-bipyridyl-κ2N,N′)cobalt(II) monohydrate
%A Jaturong Phatchimkun
%A Narongsak Chaichit
%J Acta Crystallographica Section E
%D 2011
%I International Union of Crystallography
%R 10.1107/s1600536811011305
%X In the title compound, [Co(C12H12N2)2(N3)2]¡¤H2O, the Co(II) ion is situated on a crystallographic twofold axis and adopts a distorted octahedral geometry with the two dmbpy (dmbpy = 5,5¡ä-dimethyl-2,2¡ä-bipyridyl) and the two azido ligands in a cis arrangement. The solvent water molecule and one methyl group of the dmbpy ligand are disordered over two sets of sites in a 1:1 ratio. The crystal structure is stabilized by intramolecular C¡ªH...N(dmbpy) and intermolecular O¡ªH...N(azide) hydrogen bonds.
%U http://scripts.iucr.org/cgi-bin/paper?S1600536811011305