%0 Journal Article
%T Chlorido{N-[(E)-2-(diphenylphosphanyl)benzylidene]-2-(thiophen-2-yl)ethanamine-κP}gold(I)
%A Haleden Chiririwa
%A Alfred Muller
%J Acta Crystallographica Section E
%D 2012
%I International Union of Crystallography
%R 10.1107/s1600536811052536
%X The title compound, [AuCl(C25H22NPS)], crystallizes with two independent molecules in the asymmetric unit in which the thiophene fragments are disordered over two sets of sites with 0.537 (10):0.463 (10) and 0.701 (9):0.299 (9) occupancy ratios. In both cases, the thiophene ring is rotated by approximately 180＜ for the second component. Important geometrical parameters include Au！P = 2.235 (2) and 2.237 (2)  , Au！Cl = 2.286 (2) and 2.292 (2)  , and P！Au！Cl = 177.39 (8) and 172.63 (7)＜. Weak intermolecular C！H...Cl interactions are observed in the crystal structure.
%U http://scripts.iucr.org/cgi-bin/paper?S1600536811052536