%0 Journal Article
%T Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN3)methanol]manganese(I) trifluoromethanesulfonate
%A Guido J. Reiss
%A Peter C. Kunz
%J Acta Crystallographica Section E
%D 2012
%I International Union of Crystallography
%R 10.1107/s1600536812035891
%X In the title compound, [Mn(C13H16N6O)(CO)3](CF3O3S), the MnI atom has a slightly distorted octahedral geometry. The three CO ligands have C¡ªMn¡ªC angles in the range 89.44 (10)¨C92.31 (9)¡ã, while the three N atoms of the tripodal ligand form significantly smaller N¡ªMn¡ªN angles of 82.76 (2)¨C85.51 (6)¡ã. The three N atoms of the tripodal ligand and the three carbonyl ligands coordinate facially. In the crystal, the trifluoromethanesulfonate counter anion is connected by a medium-strength O¡ªH...O hydrogen bond to the hydroxyl group of the manganese complex.
%U http://scripts.iucr.org/cgi-bin/paper?S1600536812035891