%0 Journal Article
%T Tricarbonylbis(triphenylphosphane-κP)iridium(I) hexafluoridophosphate methanol monosolvate
%A Ilana Engelbrecht
%A Hendrik G. Visser
%A Andreas Roodt
%J Acta Crystallographica Section E
%D 2012
%I International Union of Crystallography
%R 10.1107/s1600536812035593
%X In the title compound, [Ir(C18H15P)2(CO)3]PF6，CH3OH, the IrI atom is coordinated by two triphenylphosphine ligands in axial sites and three carbonyl ligands in the equatorial plane of a fairly regular trigonal bipyramid: the equatorial C！Ir！C angles range from 115.45 (9) to 126.42 (10)＜. The small deviations from the ideal tetrahedral geometry around the P atoms are illustrated by C！P！C angles ranging from 104.08 (9) to 106.46 (9)＜. In the crystal, the molecules are linked by weak C！H...F, C！H...O and C！H...π interactions.
%U http://scripts.iucr.org/cgi-bin/paper?S1600536812035593