%0 Journal Article
%T Tetrakis[μ-1,3-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ2N:N′]trisilver(I) tris(hexafluoridophosphate)
%A Chun-Wei Yeh
%A Yuh-Wen Ho
%A Hsun-Tsing Lee
%A Ju-Chun Wang
%J Acta Crystallographica Section E
%D 2012
%I International Union of Crystallography
%R 10.1107/s1600536812034721
%X In the title compound, [Ag3(C12H12N2O2)4](PF6)3, one AgI ion, lying on a twofold rotation axis, is coordinated by four N atoms from four 1,3-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted tetrahedral geometry and the other AgI ion is coordinated by two N atoms from two L ligands in a bent arrangement [N¡ªAg¡ªN = 169.03 (17)¡ã]. Two L ligands adopt a syn conformation, while the other two adopt an anti conformation. They bridge adjacent AgI ions, forming a trinuclear complex. One of the PF6  anions is half-occupied, with the P atom located on a twofold rotation axis. The PF6  anions link the complex molecules via Ag...F interactions [2.80 (2) and 2.85 (2)  ] into a polymeric chain along [100].
%U http://scripts.iucr.org/cgi-bin/paper?S1600536812034721