%0 Journal Article
%T (Benzoylacetonato-κ2O,O′)dicarbonylrhodium(I)
%A Carla Pretorius
%A Andreas Roodt
%J Acta Crystallographica Section E
%D 2012
%I International Union of Crystallography
%R 10.1107/s1600536812044893
%X In the title compound, [Rh(C10H9O2)(CO)2], a distorted square-planar coordination geometry is observed around the RhI atom, formed by the O atoms of the bidentate ligand and two C atoms from the carbonyl ligands. The RhI atom is displaced from the plane through the surrounding atoms by 0.017  . In the crystal, C¡ªH...O interaction is observed between a methyl group of the bidentate ligand and a carbonyl O atom. Metallophilic interactions [3.308 (3) and 3.461 (3)  ] between neighbouring RhI atoms are encountered in the crystal, resulting in the formation of a metal chain along the b-axis direction.
%U http://scripts.iucr.org/cgi-bin/paper?S1600536812044893