%0 Journal Article
%T Bis(μ-4,6-dimethylpyrimidine-2-thiolato)-κ3N,S:S;κ3S:N,S-bis[(triphenylphosphane-κP)silver(I)]
%A Yupa Wattanakanjana
%A Chaveng Pakawatchai
%A Sukanya Kowittheeraphong
%A Ruthairat Nimthong
%J Acta Crystallographica Section E
%D 2012
%I International Union of Crystallography
%R 10.1107/s1600536812048210
%X The dinuclear title complex, [Ag2(C6H7N2S)2(C18H15P)2], comprises two inversion-related [Ag(C6H7N2S)(C18H15P)] units. The pyrimidinethiolate anion acts both as a bridging and a chelating ligand. The AgI ions are linked via two ¦Ì2-S donor atoms, which generate a strictly planar Ag2S2 core with an Ag...Ag separation of 2.9569 (4)  . The AgI ion presents a distorted tetrahedral coordination geometry. In the crystal, weak C¡ªH...N and C¡ªH...S hydrogen bonds link the complex molecules into a two-dimensional network parallel to (010).
%U http://scripts.iucr.org/cgi-bin/paper?S1600536812048210