%0 Journal Article
%T Studies on Shape Selective Isopropylation Products of Coal Tar Naphthalene by Gas Chromatography/Mass Spectrometry<br>煤焦油萘择形异丙基化产物组成的气相色谱/质谱分析
%A ZHANG Ming-jin
%A PENG Han-bin
%A SHEN Shi-de
%A SUN Yu-han
%A CHEN Song-ying
%A <br>张铭金
%A 彭汉斌
%A 沈士德
%A 孙予罕
%A 陈诵英
%J 色谱
%D 2000
%I 
%X Shape selective isopropylation products of coal tar naphthalene over different zeolite catalysts have been studied by capillary gas chromatography/mass spectrometry (CGC/MS) combined with computerized library search and manual interpretations of mass spectra. The analytical results have shown that products mainly consisted of some monosubstituted, disubstituted and a few trisubstituted naphthalenes. Except the low activity of HZSM-5 catalyst, all other zeolite catalysts have higher activity. HY and H beta catalytic activities were the highest, and their naphthalene conversions attained to 79.12 and 55.79 percent respectively, but their selectivities for 2-isopropylnaphthalene (beta-IPN), 2, 6-diisopropylnaphthalene (2, 6-DIPN) and 2, 7-diisopropylnaphthalene (2, 7-DIPN) were too low. ZM catalysts had good activity and much better selectivity, especially for ZM4-3, of which its 2,6-DIPN/2,7-DIPN ratio was 2.97. Therefore, some zeolite catalysts are recommended for shape selective isopropylation of coal tar naphthalene.
%K capillary gas chromatography/mass spectrometry
%K coal tar naphthalene
%K shape-selective isopropylation
%K zeolite sieve<br>煤焦油萘
%K 择形异丙基化
%K 气相色谱
%K 质谱分析
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=4D81E042D77AFEC6881D14759692069C&aid=0B583E69DF493B64&yid=9806D0D4EAA9BED3&vid=13553B2D12F347E8&iid=0B39A22176CE99FB&sid=5E25104E99903E8A&eid=205BE674D84A456D&journal_id=1000-8713&journal_name=色谱&referenced_num=3&reference_num=5