%0 Journal Article %T Analysis of C_5 Fractions and Carbonyl Compounds by Capillary Gas Chromatography
C_5馏分及其羰化产物的毛细管气相色谱分析 %A He Li %A Dong Yunyu %A Li Xiumei %A Yao Cailan %A Fang Zhiya %A
何荔 %A 董运宇 %A 李秀梅 %A 姚彩兰 %A 方志亚 %J 色谱 %D 1999 %I %X We used two capillary columns with different characters--SE-54 (30 m x 0.25 mm) and Squalane (92 m x 0.24 mm) to analyse C5 fractions and carbonyl compounds in the mixtures of complex chemical composition. The physical properties of some components are very similar, especially for 1,3-cyclopentadiene and cis-1,3-pentadiene. 1,3-Cyclopentadiene in the feed will directly affect the activity of catalyst. In the past we only used SE-54 column to separate 1,3-cyclopentadiene and cis-1,3-pentadiene, but the results were unsatisfactory. Later we found that squalane column could separate them fairly good, but it could not yet separate dicyclopentadiene from 1,3-cyclopentadiene and carbonyl compounds in C5 fractions very well. In this work SE-54 capillary column and squalane capillary column were used together to analyse C5 fractions, and SE-54 column was used to analyse carbonyl compounds. The results are satisfactory. %K gas chromatography %K capillary column %K C5 fractions %K carbonyl compounds
气相色谱法 %K 碳5馏分 %K 羰化产物 %K 测定 %K 乙烯生产 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=4D81E042D77AFEC6881D14759692069C&aid=D7F5F79B7B81B862BEB8737B0CC0565C&yid=B914830F5B1D1078&vid=BCA2697F357F2001&iid=38B194292C032A66&sid=0F7768518993EDDE&eid=4D7D059FFBF006B9&journal_id=1000-8713&journal_name=色谱&referenced_num=0&reference_num=3