%0 Journal Article
%T Determination of dicofol residue in eel by gas chromatography-mass spectrometry<br>气相色谱-质谱法检测鳗鱼中三氯杀螨醇残留量
%A SU Jianfeng
%A CHEN Jing
%A CHEN Jinxing
%A ZHONG Maosheng
%A ZHANG Guangjun
%A LIU Jianjun
%A <br>苏建峰
%A 陈晶
%A 陈劲星
%A 钟茂生
%A 张光军
%A 刘建军
%J 色谱
%D 2010
%I 
%X A method was developed and applied to determine the residual dicofol in eel by gas chromatography-mass spectrometry (GC-MS). The residue was extracted from homogenized tissue with acetonitrile-water assisted by n-hexane, separated with liquid-liquid partition. A part of the supernatant was purified using solid phase extraction (Florisil column) prior to the GC-MS analysis. The determination was performed in selected ion monitoring (SIM) mode with the external calibration for quantitative analysis. Under the optimized conditions, the quantification limit of the method (S/N=10) was lower than 0.01 mg/kg. The recovery of the method for the spiked standard at the concentration of 0.01~0.1 mg/kg was 91%~105% with the relative standard deviation (RSD) of 4.3%~6.1%. The method is easy, fast, and more sensitive. The method can meet the requirement of the determination of dicofol in eel.
%K solid phase extraction (SPE)
%K gas chromatography-mass spectrometry (GC-MS)
%K dicofol
%K eel<br>固相萃取
%K 气相色谱-质谱法
%K 三氯杀螨醇
%K 鳗鱼
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=4D81E042D77AFEC6881D14759692069C&aid=89074C0E914F3DE423F2601AFEFD632E&yid=140ECF96957D60B2&vid=D3E34374A0D77D7F&iid=CA4FD0336C81A37A&sid=656F8C8401D91023&eid=7E8E8B150580E4AB&journal_id=1000-8713&journal_name=色谱&referenced_num=1&reference_num=15