%0 Journal Article %T Chromatographic Properties of Tetradecylamine Bonded Stationary Phase for Reversed-Phase Liquid Chromatography
十四烷基胺键合固定相的反相色谱性能 %A Long Yuande %A Yang Xlaoye %A Huang Tianbao %A
龙远德 %A 杨晓晔 %A 黄天宝 %J 色谱 %D 1999 %I %X A novel bonded stationary phase, tetradecylamlne bonded stationary phase(TABP), for reversed-phase HPLC was prepared by bondingl-tetradecylamlne to YWG-80 silica gel through 3-glyci- using aromatic compounds as analytes and methanol-water as binary mobile phase. The organic components and peakshape. The relative retention a for ethylbenzene-toluene was found to be 1.66 and the asymmetry factors of basic aniline, p-toluldlne and N, N- dimethylaniline were found to be 1. 26, 1. 21 and 1.10, respec-tively,with the V(methanol):V(water)=55:45 mobile phase. Aniline was eluted before phenol due to the suppress of the ion exchange activity of residual silanols by the internal masking Interaction. %K reversed-phase liquid chromatography %K stationaryphase %K alkylamine
反相液相色谱 %K 固定相 %K 烷基胺 %K 硅胶 %K 键合 %K LC %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=4D81E042D77AFEC6881D14759692069C&aid=D7F5F79B7B81B86207BF192762509053&yid=B914830F5B1D1078&vid=BCA2697F357F2001&iid=E158A972A605785F&sid=5A6705FDACED0BF9&eid=4B168891B5E5FB30&journal_id=1000-8713&journal_name=色谱&referenced_num=3&reference_num=1