%0 Journal Article %T Migration Behavior of Low-Mass Anions in Capillary Electrophoresis
常见阴离子的毛细管电泳迁移行为 %A Zheng Ping %A Fu Xiaoyun %A Lu Jiande %A
郑平 %A 傅小芸 %A 吕建德 %J 色谱 %D 1999 %I %X The dependence of effective mobility on ionic equivalent conductivity for 33 anions was studiedusing 5 mmol/L sodium chromate and 0. 5 mmol/L tetradecyltrimethylammonium bromide (TTAB) as background electrolyte. The relationship was developed between effective mobility off and carbon number ofmono-carboxylic acid and dicarboxylic acid homologues. The results showed that the effective mobility of anions increased with increasing ionic equivalent conductivity. The l/mff was linearly related to the carbon number of mono-carboxylic acid (C:--C,) and dicarboxylic acid (CZ-C,,). The correlation coefficient was more than0. 997. %K capillary electrophoresis %K anion %K migration behavior %K n-carboxylic acid
毛细管电泳 %K 阴离子 %K 迁移行为 %K 正构羧酸 %K 羧酸 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=4D81E042D77AFEC6881D14759692069C&aid=D7F5F79B7B81B8625771A3BD2CCB6FD0&yid=B914830F5B1D1078&vid=BCA2697F357F2001&iid=E158A972A605785F&sid=2E01F39B6CBD53DE&eid=9DC563A0FEFC04F9&journal_id=1000-8713&journal_name=色谱&referenced_num=0&reference_num=6