%0 Journal Article %T Thermodynamic properties of novel phenylene-bridged periodic mesoporous organosilica as high performance liquid chromatographic stationary phase
新型苯基桥键色谱固定相的热力学性质 %A Wu Liping %A Lian Dong %A Zhang Qinghe %A Li Hongmei %A
Wu L %A Lian D %A Zhang Q %A Li H %J 色谱 %D 2010 %I %X The thermodynamic properties of spherical phenylene-bridged periodic mesoporous organosilica (PMOs) as high performance liquid chromatographic stationary phase were investigated and compared with commercial grafted C18 and phenyl stationary phases.The retention behavior of several compounds of polycyclic aromatic hydrocarbons (PAHs) was investigated.The thermodynamic parameters of transfer from mobile phase to stationary phase were discussed.The results showed that the enthalpy-entropy compensation effect d... %K phenylene-bridged %K periodic mesoporous organosilica %K enthalpy-entropy compensation %K retention mechanism %K chromatographic stationary phase
苯基桥键 %K 介孔材料 %K 焓-熵补偿 %K 保留机理 %K 色谱固定相 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=4D81E042D77AFEC6881D14759692069C&aid=3A578877FB3ACA987C40A385D861470A&yid=140ECF96957D60B2&vid=D3E34374A0D77D7F&iid=DF92D298D3FF1E6E&sid=99A964928ADB4E67&eid=A7379F6713A46835&journal_id=1000-8713&journal_name=色谱&referenced_num=0&reference_num=16