%0 Journal Article
%T Determination of dichlorvos in water by microwave-assisted headspace-liquid-phase microextraction coupled with high performance liquid chromatography
微波辅助-顶空液相微萃取在线联用-高效液相色谱法测定环境水样中的敌敌畏
%A KONG Na
%A ZOU Xiaobing
%A HUANG Rui
%A XIA Zhining
%A WEI Xinyang
%A
孔娜
%A 邹小兵
%A 黄锐
%A 夏之宁
%A 魏欣旸
%J 色谱
%D 2010
%I
%X A novel method for the determination of dichlorvos in environmental water samples has been developed using microwave-assisted-headspace-liquid-phase microextraction (MAE-HS-LPME) coupled with high performance liquid chromatography (HPLC). The influences of extraction parameters in the sample matrix were investigated. Under optimized experimental conditions, the detection limit (S/N=3), the quantification limit (S/N=10) and the enrichment factor of the proposed method for the target analyte were 0.96 μg/L, 3.20 μg/L and 54, respectively. The recoveries of target analyte spiked in real water samples were 87.4%~103%. The extraction performance of MAE-HS-LPME to the target analyte was also compared with liquid-liquid extraction (LLE). The results indicated that the developed method is simple, rapid, efficient, solvent-saving, highly selective and widely applicable.
%K microwave-assisted extraction (MAE)
%K headspace-liquid-phase microextraction (HS-LPME)
%K high performance liquid chromatography (HPLC)
%K dichlorvos
%K environmental waters
微波辅助萃取
%K 顶空液相微萃取
%K 高效液相色谱
%K 敌敌畏
%K 环境水样
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=4D81E042D77AFEC6881D14759692069C&aid=52DBED41BF74FB93082C0830C93AAA2D&yid=140ECF96957D60B2&vid=D3E34374A0D77D7F&iid=59906B3B2830C2C5&sid=A0F0DDA3F8BC378D&eid=9E33BE6F309BC209&journal_id=1000-8713&journal_name=色谱&referenced_num=0&reference_num=0