%0 Journal Article
%T Synthesis of biodiesel by transition metal doped Fe/Zn double metal cyanide complex catalysts<br>过渡金属掺杂亚铁锌双金属氰化物催化合成生物柴油的研究
%A YANG Ling-mei
%A L Peng-mei
%A LUO Wen
%A LI Hui-wen
%A WANG Zhong-ming
%A YUAN Zhen-hong
%A <br>杨玲梅
%A 吕鹏梅
%A 罗文
%A 李惠文
%A 王忠铭
%A 袁振宏
%J 燃料化学学报
%D 2012
%I 
%X Effects of transition metals(La,Ce,Zr,Mn) on catalytic performance of double metal cyanide(DMC) catalysts for biodiesel synthesis were studied.The structure and performance of the catalysts were studied using XRD,FT-IR,ICP,BET et al.The experimental results showed that the DMC catalyst prepared by adding 1% of transition metal salts had higher activity.The catalyst with highest catalytic activity was prepared by adding 1% of La(NO3)3·nH2O.Under the conditions of methanol/oil mol ratio of 16∶1,catalyst amount of 2% and temperature of 160 ℃,a high yield(99.3%) of fatty acid methyl esters(FAME) was obtained within 7 h.The analytical results showed that adding 1% of transition metals did not change the molecular formula of Fe(II)-Zn double metal cyanide complex catalysts,while it improved particle dispersion,decreased particle size and increased surface area.This was the reason that transition metals promoted catalysts had higher activity.
%K transition metals
%K double metal cyanide
%K biodiesel
%K solid acid<br>过渡金属
%K 双金属氰化物
%K 生物柴油
%K 固体酸
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=C6AB115B41BD2F1616ECDB095B69B8ED&aid=EC09C1218AC1072B89D175914A2F5C11&yid=99E9153A83D4CB11&vid=1371F55DA51B6E64&iid=0B39A22176CE99FB&sid=2BA123C6EB9D54C2&eid=BC084ACE66B62CC8&journal_id=0253-2409&journal_name=燃料化学学报&referenced_num=0&reference_num=23