%0 Journal Article
%T Study on the Separation of Co 2 from Cu 2 , Cd 2 , Mn 2 , Zn 2 and Fe 3 by Extraction Chromatography<br>P204萃取色谱法对Co~(2+)的分离研究
%A Wang Yan
%A Zhou Chunshan
%A Xiong Xing''an
%A Chen Jingwen
%A <br>王艳
%A 周春山
%A 熊兴安
%A 陈景文
%J 色谱
%D 1999
%I 
%X In this paper, extraction chromatography by which Co2+ can be separated from Cu2+, Cd2+, Mn2+, Zn2+, Fe3+ is developed. The chromatographic column was 17 mm i.d. x 520 mm, containing polymers synthesized by styrene, divinylbenzene and P204 (volume fraction was 40%), with particle size of 100-200 mesh. The effects of transformation of P204 from the H(+)-form to the Na(+)-form by NaAc solution, the eluent acidity, and eluent composition were investigated. The results indicated that this extraction chromatographic method is good to separate Co2+ from Cu2+, Cd2+, Mn2+, Zn2+ and Fe3+, and the condition of separation is simple and convenient. When the P204 is transformed from the H(+)-form to the Na(+)-form by pH 4.0 NaAc (0.5 mol/L), and the column is eluted with pH 2.5 ClCHCOOH-ClCHCOONa (0.1 mol/L), the separation can be completed effectively.
%K P204 extraction chromatography
%K Co
%K 2
%K separation<br>P204萃取色谱，Co2＋，分离
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=4D81E042D77AFEC6881D14759692069C&aid=D7F5F79B7B81B862384F1FA389479AFF&yid=B914830F5B1D1078&vid=BCA2697F357F2001&iid=CA4FD0336C81A37A&sid=E514EE58E0E50ECF&eid=11B4E5CC8CDD3201&journal_id=1000-8713&journal_name=色谱&referenced_num=3&reference_num=4