%0 Journal Article
%T Sulphur analysis of household briquettes using MS and GC/MS detection systems after reductive pyrolysis<br>型煤中硫的还原热解MS和GC/MS分析(英文)
%A SPMarinov
%A MStefanova
%A VStamenova
%A LGonsalvesh
%A RCarleer
%A JYperman
%A <br>S.P.Marinov
%A M.Stefanova
%A V.Stamenova
%A L.Gonsalvesh
%A R.Carleer
%A J.Yperman
%J 燃料化学学报
%D 2006
%I 
%X The aim of the present study is to obtain more information concerning organic sulphur pollutants produced by some commercial briquettes based on coal and biomass.Reductive pyrolysis technique(APTPR),coupled "on-line" with mass spectrometer(MS) and "off-line" with GC/MS was used for qualitative and quantitative study of sulphur compounds emitted from household briquettes.By AP-TPR-GC/MS and inner standard application,prominent sulphur containing compounds were quantitatively determined.For different briquettes some peculiarities were observed.Namely,only for biobriquette low presence of dialkyl sulphides and aliphatic thiols was registered.The highest variety of organic sulphur forms was detected for lignite briquette.Oxidized sulphur compounds were not registered for the higher coal rank briquettes but the presence of different thiophenes was typical for them.
%K briquettes
%K pyrolysis
%K mass spectroscopy
%K organic sulphur<br>型煤
%K 热解
%K 质谱
%K 有机硫
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=C6AB115B41BD2F1616ECDB095B69B8ED&aid=052CB369559B23F2&yid=37904DC365DD7266&vid=339D79302DF62549&iid=38B194292C032A66&sid=4290346F7268639E&eid=7ABC4505E3960D2B&journal_id=0253-2409&journal_name=燃料化学学报&referenced_num=1&reference_num=15