%0 Journal Article
%T Tert-butylation of p-cresol catalyzed by Al-MCM-41 mesoporous molecular sieves<br>Al-MCM-41介孔分子筛催化对甲酚叔丁基化反应的研究
%A YU Xin-yu
%A LIU Cai-hua
%A CHENG Wen-ping
%A YANG Jian-guo
%A HE Ming-yuan
%A <br>于心玉
%A 刘彩华
%A 程文萍
%A 杨建国
%A 何鸣元
%J 燃料化学学报
%D 2006
%I 
%X Mesoporous molecular sieves Al-MCM-41 with n(SiO_2)/n(Al_2O_3) ratio being 20,50 and 100 were prepared.As proved by X-ray diffraction(XRD) patterns and the N_2 physical sorption,the as-synthesized Al-MCM-41 exhibited typical hexagonal structure,large surface areas and narrow pore distribution.The performance of HAl-MCM-41 as catalyst for tert-butylation of p-cresol with methyl tert-butyl-ether(MTBE) was then investigated.The effects of temperature,weight hourly space velocity(WHSV) and the feed ratio n(MTBE)/n(p-cresol) on p-cresol conversion and product selectivity were examined.The results showed that mesoporous HAl-MCM-41 molecular sieves(n(SiO_2)/n(Al_2O_3) = 20) is an efficient catalyst with high activity,selectivity and stability for the synthesis of 2-tert-butyl-p-cresol from p-cresol and MTBE by tert-butylation.
%K mesoporous HAl-MCM-41 molecular sieves
%K p-cresol
%K methyl tert-butyl-ether
%K 2-tert-butyl-p-cresol
%K catalysis<br>HAl-MCM-4介孔分子筛
%K 对甲酚
%K 甲基叔丁基醚
%K 2-叔丁基对甲酚
%K 催化
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=C6AB115B41BD2F1616ECDB095B69B8ED&aid=CCC57D80F690D9A9&yid=37904DC365DD7266&vid=339D79302DF62549&iid=B31275AF3241DB2D&sid=A8E9231F98774741&eid=8D71AF42ACD39979&journal_id=0253-2409&journal_name=燃料化学学报&referenced_num=2&reference_num=11