%0 Journal Article
%T Fe(Ⅲ)EDTA as an efficient redox cocatalyst for oxidative carbonylation of phenol to diphenyl carbonate<br>Fe(III)EDTA作为氧化羰化苯酚合成碳酸二苯酯一种有效的氧化还原催化助剂
%A Mei Fu-ming
%A Li Guang-xing
%A <br>梅付名
%A 李光兴
%J 燃料化学学报
%D 2006
%I 
%X The synthesis of diphenyl carbonate (DPC) by oxidative carbonylation of phenol was studied. Fe(Ⅲ)EDTA was found to be efficient in PdCl2/Fe(Ⅲ)EDTA/1,4-benzoquinone (BQ)/ tetrabutylammonium bromide (TBAB) catalyst system. The role of each component in the catalyst system was discussed. A catalytic mechanism was proposed. The optimum reaction temperature for oxidative carbonylation of phenol to DPC was 100℃～120℃. When the reaction was catalyzed over PdCl2/Fe(Ⅲ)EDTA/BQ/Bu4NBr, at 100℃,pCO=2.0MPa,pO2=0.5MPa,phenol 0.5 mol, PdCl2 0.28mmol, n(PdCl2)∶n(redox cocat.)∶n(BQ)∶n(Bu4NBr)=1∶1∶10∶40, 4 A molecular sieve 5.0 g, 4 h, the yield and selectivity of DPC were 8.35% and 97.5% respectively. High pressure was favorable for the production of DPC.
%K diphenyl carbonylation
%K oxidative carbonylation
%K palladium chloride<br>Fe(Ⅲ)EDTA
%K 碳酸二苯酯
%K 氧化羰化
%K 氯化钯
%K Fe(Ⅲ)EDTA
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=C6AB115B41BD2F1616ECDB095B69B8ED&aid=C4DBA4E4A7EBA2FD&yid=37904DC365DD7266&vid=339D79302DF62549&iid=B31275AF3241DB2D&sid=B60458D1AE87BCD1&eid=547991B346A6585E&journal_id=0253-2409&journal_name=燃料化学学报&referenced_num=0&reference_num=26