%0 Journal Article
%T In-situ synthesis of ZSM-5 on silica gel and studies on its catalytic activity<br>硅胶原位合成ZSM-5分子筛及其催化性能的研究
%A FENG Hui
%A CHEN Yan-hong
%A LI Chun-yi
%A SHAN Hong-hong
%A <br>冯会
%A 陈艳红
%A 李春义
%A 山红红
%J 燃料化学学报
%D 2008
%I 
%X ZSM-5 was in-situ synthesized on silica gel using n-butylamine as the template and characterized by XRD, SEM, FT-IR and N2 adsorption. The results indicated that the synthesized sample not only has a composite structure with ZSM-5 and silica gel, but also retains the shape of silica gel microsphere. To obtain detailed information on the rules of synthesized chemistry, the effects of SiO2/Al2O3 of initial gel, H2O/SiO2, BuNH2/SiO2, OH /SiO2, crystallization time and crystallization temperature on ZSM-5 crystallinity were systematically studied. The composite materials were tested in a micro fixed-bed reactor, using Daqing Vacuum Gasoline Oil (VGO) as the feedstock. The results indicated that the composite structure zeolite yields more light olefins and has good selectivity to light olefins.
%K composite molecular sieves
%K ZSM-5
%K silica gel
%K in-situ synthesis
%K light olefins<br>复合结构分子筛
%K ZSM-5
%K 硅胶
%K 原位合成
%K 低碳烯烃
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=C6AB115B41BD2F1616ECDB095B69B8ED&aid=813EA332B634B336656436C02D4B461D&yid=67289AFF6305E306&vid=933658645952ED9F&iid=0B39A22176CE99FB&sid=EB552E4CFC85690B&eid=7CE3F1F20DE6B307&journal_id=0253-2409&journal_name=燃料化学学报&referenced_num=0&reference_num=10