%0 Journal Article
%T Effect of metal loadings on catalytic dry oxidation of phenol by CuO/AC catalyst-sorbents<br>金属担载量对CuO/AC干法催化氧化苯酚的影响
%A ZHAO Jiang-hong
%A LIU Zhen-yu
%A <br>赵江红
%A 刘振宇
%J 燃料化学学报
%D 2006
%I 
%X Adsorption of organic pollutants from waste waters at ambient conditions followed by catalytic dry oxidation of these adsorbed materials at low temperatures has been reported to be a promising method for the treatment of toxic and/or bio-refractory wastewaters.This work mainly investigated the effect of metal loadings on the catalytic activity of the CuO/AC catalyst-sorbent used for the catalytic dry oxidation of phenol through temperature-programmed oxidation(TPO) and consecutive adsorption-oxidation experiments. The results indicate that increasing metal loadings promotes the phenol oxidation activity of the CuO/AC catalyst-sorbent,and enhances the affinity between the phenol and the CuO/AC catalyst-sorbent.This makes the adsorbed phenol desorb and/or de-associatively desorb from the catalyst-sorbent difficult.In addition,the ignition activity of the CuO/AC catalyst-sorbent itself is improved with increasing metal loadings.According to these results,it is clear that there is a proper metal loadings range of 3 ~ 5% for the CuO/AC catalyst-sorbent used for catalytic dry oxidation of phenol,which is calculated as the Cu weight percent.
%K metal loadings
%K CuO/AC catalyst-sorbent
%K catalytic dry oxidation
%K phenol<br>担载量
%K CuO/AC催化-吸附剂
%K 干法催化氧化
%K 苯酚
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=C6AB115B41BD2F1616ECDB095B69B8ED&aid=5D9AA4900A245234&yid=37904DC365DD7266&vid=339D79302DF62549&iid=CA4FD0336C81A37A&sid=80A07035DF96B0C4&eid=E203FB1A272C9DD2&journal_id=0253-2409&journal_name=燃料化学学报&referenced_num=0&reference_num=13