%0 Journal Article
%T Synthesis, crystal structure and thermal behavior of Rb(NTO) · H2O<br>
%A Mancheng Hu
%A Shiyang Gao
%A Zhihong Liu
%A Jirong Song
%A Shuping Xia
%A Kaibei Yu
%A <br>
%J 科学通报(英文版)
%D 2001
%I 
%X The Rb(NTO)·H2O crystal has been synthesized by reaction of 3-nitro-1,2,4-triazole-5-one (NTO) with Rb2CO3 in aqueous solution. Its crystal structure has been determined. The crystal belongs to monoclinic system. Crystal structure data: space group P21 / n; a = 0.633 0(1), b = 0.824 1(2), c =1.296 4(3) nm; β= 97.90(1)°; V = 0.669 9 (2) nm3 , Z = 4, Dc = 2.306 g/cm3, μ= 7.365 nm-1, F (000) = 448. An eight coordinated compound is formed between Rb+ with oxygen atoms and nitrogen atoms. A layer structure is formed by coordination bonds and hydrogen bonds. The thermal decomposition mechanism of this coordination compound is discussed .
%K Rb-NTO
%K coordination compound
%K crystal structrue
%K thermal decomposition<br>
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=01BA20E8BA813E1908F3698710BBFEFEE816345F465FEBA5&cid=96E6E851B5104576C2DD9FC1FBCB69EF&jid=DD6615BC9D2CFCE0B6F945E8D5314523&aid=64FB18631B464B6F6EA467889CD8B05B&yid=14E7EF987E4155E6&vid=D997634CFE9B6321&iid=CA4FD0336C81A37A&sid=94E7F66E6C42FA23&eid=2A3781E88AB1776F&journal_id=1001-6538&journal_name=科学通报(英文版)&referenced_num=0&reference_num=0