%0 Journal Article %T Electron theory study on mechanism of action of cobaltin Fe-Co-Cr based high-alloy steel
Electron theory study on mechanism of action of cobalt in Fe-Co-Cr based high-alloy steel %A Peijie Li %A Yuhua Xiong %A Shuxun Liu %A Daben Zeng %A
LIPeijie %A XIONGYuhna等 %J 科学通报(英文版) %D 2003 %I %X The valence electron structure of martensite in Fe-Co-Cr based high-alloy steel is calculated using the em-pirical electron theory of solids and molecules (EET). The results show that the incorporation of cobalt leads to a rise in nA from 0.3835 to 0.4684, which enhances the bonding forces between atoms in a-Fe matrix. Meanwhile, the incorporation of Co changes the valence electron structure of segregated structure units formed by C and other alloying elements, and increases nA for the segregated units containing C-Me sig-nificantly, resulting in changing the precipitation behavior of the secondary phases during tempering and strengtheningthe resistance to tempering. %K Fe-Co-Cr based high-alloy steel %K cobalt %K valence elec-tronic structure
钴 %K 价电子结构 %K 碳 %K 铁 %K 固溶体 %K 相互作用 %K Fe-Co-Cr基高合金钢 %K 电子理论 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=01BA20E8BA813E1908F3698710BBFEFEE816345F465FEBA5&cid=96E6E851B5104576C2DD9FC1FBCB69EF&jid=DD6615BC9D2CFCE0B6F945E8D5314523&aid=FECF2DA37621532A395BB784A76A6FFA&yid=D43C4A19B2EE3C0A&vid=B6DA1AC076E37400&iid=0B39A22176CE99FB&sid=3D9746C06EC12B45&eid=AA27B676BFCAA4BE&journal_id=1001-6538&journal_name=科学通报(英文版)&referenced_num=0&reference_num=7