%0 Journal Article
%T Electron theory study on mechanism of action of cobaltin Fe-Co-Cr based high-alloy steel
Electron theory study on mechanism of action of cobalt in Fe-Co-Cr based high-alloy steel
%A Peijie Li
%A Yuhua Xiong
%A Shuxun Liu
%A Daben Zeng
%A
LIPeijie
%A XIONGYuhna等
%J 科学通报(英文版)
%D 2003
%I
%X The valence electron structure of martensite in Fe-Co-Cr based high-alloy steel is calculated using the em-pirical electron theory of solids and molecules (EET). The results show that the incorporation of cobalt leads to a rise in nA from 0.3835 to 0.4684, which enhances the bonding forces between atoms in a-Fe matrix. Meanwhile, the incorporation of Co changes the valence electron structure of segregated structure units formed by C and other alloying elements, and increases nA for the segregated units containing C-Me sig-nificantly, resulting in changing the precipitation behavior of the secondary phases during tempering and strengtheningthe resistance to tempering.
%K Fe-Co-Cr based high-alloy steel
%K cobalt
%K valence elec-tronic structure
钴
%K 价电子结构
%K 碳
%K 铁
%K 固溶体
%K 相互作用
%K Fe-Co-Cr基高合金钢
%K 电子理论
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=01BA20E8BA813E1908F3698710BBFEFEE816345F465FEBA5&cid=96E6E851B5104576C2DD9FC1FBCB69EF&jid=DD6615BC9D2CFCE0B6F945E8D5314523&aid=FECF2DA37621532A395BB784A76A6FFA&yid=D43C4A19B2EE3C0A&vid=B6DA1AC076E37400&iid=0B39A22176CE99FB&sid=3D9746C06EC12B45&eid=AA27B676BFCAA4BE&journal_id=1001-6538&journal_name=科学通报(英文版)&referenced_num=0&reference_num=7