%0 Journal Article
%T Crystal structure and magnetism of the binuclear Gd(III) complex Gd2(C12H8N2)2(C6H5COO)6<br>
%A NIU Shuyun
%A JIN Jing
%A JIN Xianglin
%A CONG Yao
%A YANG Zhongzhi
%A <br>
%J 科学通报(英文版)
%D 2000
%I 
%X In the medium of H2O, C2H5OH and HAC, the reaction of Gd(NO3)3·6H2O with C6H5COONa and C12H8N2 produced a novel binuclear Gd(III) complex in formula Gd2(C12H8N2)2 (C6H5COO)6]. Crystallographic data: crystal system, triclinic; space group, P1; unit cell dimensions, a=1.191 9(2) nm,b =1.244 2(2) nm,c = 1.080 4(2) nm, α = 93.57(3)°, β= 113.33(3)°, γ= 105.06(3)°, Z=l. The finalR =0.037 6. The magnetic measurement of the crystal powder in the temperature region of 1.5–300 K shows that this complex possesses antiferromagnetic property with fitting magnetic parametersJ =  0.471 andg =1.975.
%K binuclear Gd(III) complex
%K crystal structure
%K magnetism<br>
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=01BA20E8BA813E1908F3698710BBFEFEE816345F465FEBA5&cid=96E6E851B5104576C2DD9FC1FBCB69EF&jid=DD6615BC9D2CFCE0B6F945E8D5314523&aid=F344D9B730B6B942367AB1F14BC4697D&yid=9806D0D4EAA9BED3&vid=94E7F66E6C42FA23&iid=5D311CA918CA9A03&sid=C19D5524C51D7FE4&eid=FD6137FFCE59D193&journal_id=1001-6538&journal_name=科学通报(英文版)&referenced_num=0&reference_num=19