%0 Journal Article %T Mesoporous zeolite SBA-15 supported nickel diimine catalysts for ethylene polymerization %A GUO Chao %A ZHANG Dao %A JIN Guoxin %A
GUOChao %A ZHANGDao %A JINGuoxin %J 科学通报(英文版) %D 2004 %I %X The novel mesoporous zeolite SBA-15 is successfully used as the support to immobilize late-transition metal nickel diimine catalyst, both in physical and chemical methods, EA, ICP, FT-IR and XRD are applied to characterizing these supported catalysts. The results of ethylene polymerization reveal that these supported catalysts have high catalytic activity as their homogenous counterpart does, moreover, polyethylene with a fibrous morphology is pro-duced due to the channel effect of support, and both the molecular weight and molecular weight distributions of polymers are increased greatly. %K mesoporous zeolite %K SBA-15 %K heterogenous catalysis %K nickel diimine catalyst %K olefin polymerization
中孔性沸石 %K 二亚胺 %K 催化剂 %K 镍 %K 聚乙烯 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=01BA20E8BA813E1908F3698710BBFEFEE816345F465FEBA5&cid=96E6E851B5104576C2DD9FC1FBCB69EF&jid=DD6615BC9D2CFCE0B6F945E8D5314523&aid=C7647730B0387B22F4C4B73E0DCA015A&yid=D0E58B75BFD8E51C&vid=2A3781E88AB1776F&iid=38B194292C032A66&sid=D537C66B6404FE57&eid=82722E2B785EBF0D&journal_id=1001-6538&journal_name=科学通报(英文版)&referenced_num=3&reference_num=15