%0 Journal Article
%T Bond valence parameters linearly dependent on the molybdenum oxidation states<br>
%A CHEN Mingdan
%A ZHOU Zhaohui
%A HU Shengzhi
%A <br>
%J 科学通报(英文版)
%D 2002
%I 
%X Based on the available crystal data, a linear correlation between R0, the bond valence parameter for a Mo-containing chemical bond, and the Mo oxidation state n was developed for the first time. Using the "universal" value of the parameter B = 0.037 nm, the linear equations of R0-n for Mo-X (X: O, S, N, Cl and F) bonds were established. The oxidation-state independent Mo-O bond valence parameters, R0 = 0.18788 nm and B = 0.03046 nm, published recently have been shown to be a special case of the linearly correlated functions. Some bond valence sum calculations in compounds containing only Mo-O bonds using these para- meters are presented.
%K bond valence parameter
%K Mo-O bond
%K oxidation state
%K valence sum rule<br>
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=01BA20E8BA813E1908F3698710BBFEFEE816345F465FEBA5&cid=96E6E851B5104576C2DD9FC1FBCB69EF&jid=DD6615BC9D2CFCE0B6F945E8D5314523&aid=6418539B4A46E5636CD0FEC93AFB20BB&yid=C3ACC247184A22C1&vid=F4B561950EE1D31A&iid=59906B3B2830C2C5&sid=32491EEEE0A8C927&eid=90C2E72D2E105FF5&journal_id=1001-6538&journal_name=科学通报(英文版)&referenced_num=0&reference_num=11