%0 Journal Article
%T Electrochemistry study on PEO-LiClO4-ZSM5 composite polymer electrolyte
%A Jingyu Xi
%A Xiaomei Ma
%A Mengzhong Cui
%A Xiaobin Huang
%A Zhen Zheng
%A Xiaozhen Tang
%A <br>XI Jingyu
%A MA Xiaomei
%A CUI Mengzhong
%A HUANG Xiaobin
%A ZHENG Zhen & TANG Xiaozhen . School of Chemistry and Chemical Technology
%A Shanghai Jiao Tong University
%A Shanghai
%A China
%A . School of Chemistry and Chemical Technology
%A Qingdao University
%A Qingdao
%A China Correspondence should be addressed to Tang Xiaozhen
%J 科学通报(英文版)
%D 2004
%I 
%X A novel all solid-state composite polymer electrolyte, PEO-LiClO4-LiZSM5, by using “shape-selective” molecular sieves ZSM-5 as filler was obtained by the solvent casting method. The experimental results showed that the addition of LiZSM5 could enhance the ionic conductivity of the pristine PEO-LiClO4 electrolyte, the ionic conductivity of PEO10-LiClO4-10%LiZSM5 achieved 1.4 × 10 5 S cm 1 at 25°C. Lithium ion transference number was tested by AC impedance combined with the steady-state current method, the results showed that LiZSM5 could improve the Li+ transference number of the CPE effectively. The broad electrochemical stability window ensured the use of PEO-Li-ClO4-LiZSM5 as electrolyte materials for all solid-state rechargeable lithium ion batteries.
%K composite polymer electrolyte
%K ZSM-5
%K ionic conductivity
%K lithium ion transference number
%K electrochemical stability window<br>电化学
%K PEO-LiClO4-ZSM5
%K 合成聚合体电解液
%K 离子电导性
%K 锂离子转换数目
%K 稳定性
%K 锂离子电池
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=01BA20E8BA813E1908F3698710BBFEFEE816345F465FEBA5&cid=96E6E851B5104576C2DD9FC1FBCB69EF&jid=DD6615BC9D2CFCE0B6F945E8D5314523&aid=C25C92BB45657DFF4D73678675A8A6BC&yid=D0E58B75BFD8E51C&vid=2A3781E88AB1776F&iid=5D311CA918CA9A03&sid=A1BB529A18D3A83E&eid=7B927C26AC9ED104&journal_id=1001-6538&journal_name=科学通报(英文版)&referenced_num=0&reference_num=14