%0 Journal Article
%T Metallic Nanoparticle Block Copoloymer Vesicles with Enhanced Optical Properties
%A Juan Leonardo Martinez-Hurtado
%J Nanomaterials
%D 2011
%I MDPI AG
%R 10.3390/nano1010020
%X The fabrication and characterization of template silver nanoshell structures and the encapsulation of gold nanoparticles using biocompatible poly(oxyethylene)-poly(butylene) diblock co-polymer vesicles is described in this work. These vesicles have a narrow diameter size distribution around 200 nm. Silver nanoparticles ( £¿ = 1¨C10 nm) functionalized with decanethiol were successfully entrapped in the hydrophobic membrane and non-functionalized gold nanoparticles ( £¿ = 3.0¨C5.5 nm) were encapsulated in the vesicle core. Transmission Electron Microscopy confirms the localisation of the particles; silver functionalized nanoparticles appear to thicken the vesicle membrane as shown with TEM image analysis. The enhancement of the optical properties is confirmed using transmission spectrophotometry; the 430 nm plasmon resonance peak of the silver nanoparticles was replaced by a broader extinction spectrum to beyond 700 nm (O.D. = 0.8). For a number density of 4.8 x 10 12 mL -1 the scattering cross section was calculated to be 0.92 x 10 -4 ¦Ìm 2 with a scattering coefficient of 0.44 mm -1. The measurements indicate scattering cross section of 3.8 x 10 -5 ¦Ìm 2, attenuation coefficient of 0.18 mm -1 and extinction efficiency equal to 1.2 x 10 -3. Stable and biocompatible block co-polymer vesicles can potentially be used as plasmon-resonant optical contrast agents for biomedical applications.
%K block copolymer
%K metallic nanoparticle
%K optical properties
%K encapsulation
%U http://www.mdpi.com/2079-4991/1/1/20