%0 Journal Article %T HYDROGEN STORAGE PROPERTIES AND CRYSTAL STRUCTURE OF Ti-Cr BASED ALLOYS
Ti-Cr基合金的储氢性能及晶体结构 %A WANG Yang %A ZHANG Yan %A WANG Xinhua %A CHEN Changpin %A
汪洋 %A 张琰 %A 王新华 陈长聘 %J 金属学报 %D 2006 %I %X The hydrogen storage properties and crystal structures of Ti1+xCr1.2Mn0.8(x=0.0, 0.1, 0.2, 0.3) and Ti1+xCr1.2Mn0.8-yMy (M=Fe, Ni, Cu, V, VFe; x=0.0, 0.1; y=0.1, 0.3) have been studied systematically. XRD patterns proved that the two series of hydrogen storage alloys have the same crystal structure, C14(MgZn2) typed Laves phase, which is suitable for hydrogen absorption and desorption with great amount. The lattice parameter a, c and cell volume V increase with increasing Ti content and substitution of Mn by Fe, Ni, Cu, V and VFe, while the hysteresis factors of P-C-T curves decrease. In order to develop hydrogen storage alloys for the metal hydride hydrogen compressor (MHHC), the effect of the substitution elements have been investigated, and the results show that both alloys, TiCr1.2Mn0.5Fe0.3 and Ti1.1Cr1.2Mn0.5Cu0.3, have high hydrogen storage capacities and high compression ratios. %K Ti-Cr base hydrogen storage alloy %K hydrogen storage property %K crystal structure %K compression property
Ti-Cr基合金 %K 储氢性能 %K 晶体结构 %K 压缩特性 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=AB188D3B70B071C57EB64E395D864ECE&jid=B061E1135F1CBDEE96CD96C109FEAD65&aid=3A345A36307F1C84&yid=37904DC365DD7266&vid=ECE8E54D6034F642&iid=B31275AF3241DB2D&sid=9A596D09E9486F3E&eid=6C62BFE34266FA92&journal_id=0412-1961&journal_name=金属学报&referenced_num=0&reference_num=14