%0 Journal Article
%T MODIFYING EFFECTS OF PEGS AND SDS ON SYNTHESIS OF NICKLE NANOCRYSTALS IN POLYALCOHOL<br>修饰剂对液相还原法制备的纳米镍粒子形貌与尺寸的影响
%A Zhang X F
%A <br>张锡凤
%A 殷恒波
%A 程晓农
%A 赵歆
%A 蒋忠桂
%A 王爱丽
%J 金属学报
%D 2006
%I 
%X Size- and shape-controlled Ni nanoparticles were synthesized using nickel acetate as precursor, 1, 2-propanediol as solvent and reducing agent, sodium hydroxide as pH adjusting agents, and surfactants PEG (polyethylene glycols) and SDS (sodium dodecyl sulfate) as modifiers. The as-prepared Ni nanoparticles were characterized by TEM, XRD and Fourier transform infrared (FTIR) spectroscopy. The presence of modifiers is crucial for the synthesis of size- and shape-controlled phase pure Ni nanoparticles. The modification effects of single modifiers such as PEGs and SDS, and their composites were investigated and analyzed. Among single modifiers, the PEG-200 or PEG-600 is beneficial to fabricating irregular snowflake-like crystals, PEG-2000 beneficial to synthesizing dodecahedra crystals, PEG-6000 beneficial to synthesizing triangular crystals, and SDS beneficial to fabricating dodecahedra crystals and irregular snowflake-like crystals with smaller average particle size. Among the composite modifiers, coexisting of SDS and PEG-600 or PEG-6000 is beneficial to fabricating irregular snowflake-like crystals with bigger average particle size. The effects of the modifiers play an important role in the synthesis of Ni nanoparticles certified by FTIR spectroscopy.
%K liquid phase reduction method
%K nickel nanoparticle
%K polyethylene glycol (PEG)
%K soidum dodecyl sulfate (SDS)<br>液相还原法
%K 纳米镍
%K 聚乙二醇
%K 十二烷基硫酸钠
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=AB188D3B70B071C57EB64E395D864ECE&jid=B061E1135F1CBDEE96CD96C109FEAD65&aid=CBE4B556D7030859&yid=37904DC365DD7266&vid=ECE8E54D6034F642&iid=E158A972A605785F&sid=663FF78B2ADE7A2D&eid=3BAAE0DA6093AC05&journal_id=0412-1961&journal_name=金属学报&referenced_num=4&reference_num=19