%0 Journal Article %T EXTRACTION KINETICS, MICELLIZATION AND INTERFACIAL CHARACTERISTICS OF A NEW MIXED EXTRACTANT SYSTEM
新混合萃取剂体系的萃取动力学和胶团化作用 %A YU Jingfen %A JI Chen %A PAN Xiaomei %A XIONG Yigang Tsinghua University %A Beijing %A
于静芬 %A 吉晨 %A 潘小玫 %A 熊毅钢 %J 金属学报 %D 1990 %I %X Study was made of the micellization, interfacial characteristics and extraction kinetics of a newly developed D_2 EHPA-H_2 RPA-Al~(3+) mixed system. In the system, more vigorous micellization and better interfacial acitivity of H_2RPA were revealed. While it has a decreasing tendency to micellization and inter facial activity with increase of D_2EHPA content. The adsorption behaviour of H_2RPA at the in- terface is quite contrary to that of D_2EHPA. The controlling mechanism of extra- ction kinetics for the non-micella mixed extractant system was confirmed as the type of interfacial chemical reaction, and the equation for extraction rate was thus obtained. This non-micella extraction system of mixed extractants seems to be favourable to hydrometallurgy. %K D_2EHPA-H_2RPA-Al~(3+) extraction system %K Al %K micellization %K interfacial kinetics
萃取 %K D2EHPA %K H2RPA %K Al %K 动力学 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=AB188D3B70B071C57EB64E395D864ECE&jid=B061E1135F1CBDEE96CD96C109FEAD65&aid=1857A51189BB45719203DF5CD1C158CB&yid=8D39DA2CB9F38FD0&vid=96C778EE049EE47D&iid=B31275AF3241DB2D&sid=656F8C8401D91023&eid=CFAC5CB624A41AFD&journal_id=0412-1961&journal_name=金属学报&referenced_num=1&reference_num=4