%0 Journal Article
%T VARIATIONAL CALCULATION OF THERMODYNAMIC PROPERTIES OF SUPERCOOLED LIQUID METALS<br>过冷液态金属热力学性质的变分计算
%A SHEN Tao
%A WANG Jingtang Institute of Metal Research Academia Sinica
%A Laboratory of Rapidly Solidified Non-Equilibrium Alloys
%A Shenyang professor
%A <br>沈涛
%A 王景唐
%J 金属学报
%D 1990
%I 
%X By means of the Gibbs-Bogoliubov (GB) thermodynamical variationalcalculation, the thermodynamical properties of the liquid metals as supercooled sta-te, such as Al, Ga, Tl in the 3rd family of periodic table and transition metal Tiwere calculated using the hard-sphere (HS) system as reference. The values of meanatomic volume, Helmholtz free energy, internal energy and entropy as well asspecific heat at constant volume, isothermal bulk modulus, thermal expansion co-efficient and specific heat under constant pressure were determined. The glass tran-sition temperature, T_g, is easily obtained from c_p-T plot. The glass forming abili-ty for metal can be predicted with T_g/T_m, which is in agreement with the experi-mental results.
%K supercooled metal
%K hard-sphere system
%K thermodynamic variational calculation
%K specific heat
%K glass transition temperature<br>液态
%K 金属
%K 热力学
%K 变分计算
%K 等压
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=AB188D3B70B071C57EB64E395D864ECE&jid=B061E1135F1CBDEE96CD96C109FEAD65&aid=0F95081300634698DA06C505DC5301CA&yid=8D39DA2CB9F38FD0&vid=96C778EE049EE47D&iid=38B194292C032A66&sid=EFD65B51496FB200&eid=F122871CC7EC92DC&journal_id=0412-1961&journal_name=金属学报&referenced_num=0&reference_num=1