%0 Journal Article %T Degradation mechanism of aniline by ozonation catalysis
臭氧催化氧化降解苯胺的机理 %A Ning Jun %A Chen Liwei %A Cai Tianming %A
宁军 %A 陈立伟 %A 蔡天明 %J 环境工程学报 %D 2013 %I %X We compared the degradation efficiency of aniline by ozonation alone and catalyzed ozonation, and ananylzed the change of products in oxidation process by LC-MS. The results showed that MnO2-CuO-CeO2/zeolite catalyst could effectively improve the degradation rate of aniline by ozonation, and when original aniline concentration was 200 mg/L, the removal efficiency of aniline increased from 75% to 89% after 20 min; LC-MS analysis showed that the degradation products of aniline by catalyzed ozonation are successively p-benzoquinonimine, p-benzoquinone, maleic acid and oxalic acid; and according to that, the degradation pathway of aniline by ozonation is inferred. %K aniline %K MnO2-CuO-CeO2/zeolite catalysis %K ozonation %K degradation pathway
苯胺 %K MnO2-CuO-CeO2/沸石催化 %K 臭氧氧化 %K 降解途径 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=92E6F4267FD4CBCB51B1E49E014D8054&jid=3567BD61129AA59043F5DE01F8815DB5&aid=4D6BB6A422263A45D5AFA97DF8C2E447&yid=FF7AA908D58E97FA&vid=DF92D298D3FF1E6E&iid=0B39A22176CE99FB&sid=CEFF71AEB051114C&eid=CF0706A3E35031F6&journal_id=1673-9108&journal_name=环境工程学报&referenced_num=0&reference_num=20