%0 Journal Article
%T Dynamic and thermodynamic phenomenon of cation exchange membrane of copper ion<br>阳离子交换膜对Cu2+离子交换的动力学及热力学研究
%A Xie Dehu
%A Shi Zhou
%A Chen Shiyang
%A <br>谢德华
%A 施周
%A 陈世洋
%J 环境工程学报
%D 2012
%I 
%X Dynamic and thermodynamic phenomenon of the cation membrane exchanging of copper ion was studied.It was found that when the temperature was 25℃ and pH of the solution was 6,the exchange capacity of ion-exchange membrane for Cu2+ was 0.506 mmol/g.The ion exchange rate increased with increasing of the initial concentration of copper ion,or temperature and stirring speed.Ion exchange process has a good results fitted with a reaction rate equation.△G0<0 indicated that the ion exchange reaction can occur spontaneously.△H0m>0 indicated that exchange reaction was endothermic.△S0>0 indicates that exchange reaction was an entropy increased reaction.
%K cation exchange membrane
%K copper ion
%K dynamics
%K thermodynamics<br>阳离子交换膜
%K 铜离子
%K 动力学
%K 热力学
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=92E6F4267FD4CBCB51B1E49E014D8054&jid=3567BD61129AA59043F5DE01F8815DB5&aid=078384E9FE9084EA50EB9EA6E4DBCE21&yid=99E9153A83D4CB11&vid=B31275AF3241DB2D&iid=5D311CA918CA9A03&sid=9E137153D4946F03&eid=2B9069602EEA043E&journal_id=1673-9108&journal_name=环境工程学报&referenced_num=0&reference_num=0