%0 Journal Article
%T Catalytic ozonation of phenol in aqeuous solution coupled with nickel oxide-loaded activated carbon<br>NiO/AC催化臭氧氧化去除水中的苯酚
%A Wang Yiping
%A Lan Yuecun
%A Rao Yifei
%A Luo Hanjin
%A <br>王益平
%A 蓝月存
%A 饶义飞
%A 罗汉金
%J 环境工程学报
%D 2010
%I 
%X Nickel oxide-loaded activated carbon (NiO/AC) was prepared by the method of an incipient wetness impregnation at low temperature. The degradation of phenol by combined catalytic oxidation of NiO/AC and ozone under different pH and concentrations of t-BuOH was investigated. The crystal structure, surface morphology and textural properties of AC and NiO/AC were characterized by XRD, SEM and BET. The results showed that nickel was loaded on the surface of activated carbon in the form of rod-like nickel oxide. The surface area of NiO/AC decreased by 47.9% compared to that of AC. The reaction of O3/NiO/AC catalyzed ozonation of phenol followed the hydroxyl radical reaction mechanism. The removal efficiency of phenol was 29% higher than that of ozone.The removal rate of phenol has the positive correlation with the solution pH. It is confirmed that the catalytic performance of NiO/AC was stable, the maximum nickel ion concentration was 7 mg/L, which can be reused for several times.
%K catalytic ozonation
%K hydroxyl radical
%K NiO/AC
%K phenol<br>催化臭氧氧化
%K 羟基自由基
%K NiO/AC
%K 苯酚
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=92E6F4267FD4CBCB51B1E49E014D8054&jid=3567BD61129AA59043F5DE01F8815DB5&aid=45F1F8D26E634D45A6DFD5B1EA873140&yid=140ECF96957D60B2&vid=E158A972A605785F&iid=708DD6B15D2464E8&sid=C9CB60BA1E75B616&eid=6070D5F75410BA41&journal_id=1673-9108&journal_name=环境工程学报&referenced_num=0&reference_num=0