%0 Journal Article %T Study on catalytic activity and CO2 selectivity for naphthalene oxidation over CuO(-CeO2)/SBA-15
CuO(-CeO2)/SBA-15对萘氧化的催化活性及CO2选择性研究 %A Xu Li %A Wang Jing %A Wu Junliang %A Huang Bichun %A Ye Daiqi %A
徐丽 %A 王静 %A 吴军良 %A 黄碧纯 %A 叶代启 %J 环境工程学报 %D 2010 %I %X CuO and CuO-CeO_2supported mesoporous molecular sieves SBA-15 were prepared using an im-pregnation method, and the catalysts were characterized by BFT,XRD,TPR and XPS techniques. The catalytic activity and CO_2 selectivity for the complete oxidation of naphthalene were investigated. The results show that CuO is dispersed highly on the mesoporous molecular sieves, CeO_2improves CuO dispersion and lower TPR re-duction temperature. Besides, the total conversion of naphthalene to CO_2 is not achieved over the CuO/SBA-15catalyst and CO_2 yield is 60% at 380 ℃ . It is concluded that CeO_2 plays an important role in promoting carbon balance and catalyst stability. Naphthalene conversion to CO_2 of 99% is obtained over the 15% CuO-15% CeO_2/ SBA-15 catalyst at 325 ℃ . %K VOCs %K catalytic oxidation %K mesoporous molecular sieves %K naphthalene
VOCs %K 催化氧化 %K 介孔分子筛 %K 萘 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=92E6F4267FD4CBCB51B1E49E014D8054&jid=3567BD61129AA59043F5DE01F8815DB5&aid=4CA082574C504254F1068730D7A55CA2&yid=140ECF96957D60B2&vid=E158A972A605785F&iid=0B39A22176CE99FB&sid=117BC32987199759&eid=5A735990D5DE8BF4&journal_id=1673-9108&journal_name=环境工程学报&referenced_num=0&reference_num=17