%0 Journal Article
%T Isolation, identification, Pb(II) biosorption isotherms and kinetics of a lead adsorbing Penicillium sp. MRF-1 from South Korean mine soil
%A Natarajan Velmurugan
%A Grim Hwang
%A Muthuswamy Sathishkumar
%A Tae Kie Choi
%A Kui-Jae Lee
%A Byung-Taek Oh
%A Yang-Soo Lee
%A
%J 环境科学学报(英文版)
%D 2010
%I
%X A heavy metal contaminated soil sample collected from a mine in Chonnam Province of South Korea was found to be a source of heavy metal adsorbing biosorbents. Chemical analyses showed high contents of lead (Pb) at 357 mg/kg and cyanide (CN) at 14.6 mg/kg in the soil. The experimental results showed that Penicillium sp. MRF-1 was the best lead resistant fungus among the four individual metal tolerant fungal species isolated from the soil. Molecular characterization of Penicillium sp. MRF-1 was determined using ITS regions sequences. E ects of pH, temperature and contact time on adsorption of Pb(II) by Penicillium sp. MRF-1 were studied. Favorable conditions for maximum biosportion were found at pH 4 with 3 hr contact time. Biosorption of Pb(II) gradually increased with increasing temperature. E cient performance of the biosorbent was described using Langmuir and Freundlich isotherms. Adsorption kinetics was studied using pseudo first-order and pseudo second-order models. Biosorbent Penicillium sp. MRF-1 showed the maximum desorption in alkali conditions. Consistent adsorption/desorption potential of the biosorbent in repetitive cycles validated the e cacy of it in large scale. SEM studies given notes on surface modification of fungal biomass under metal stress and FT-IR results showed the presence of amino groups in the surface structure of the biosorbent. In conclusion, the new biosorbent Penicillium sp. MRF-1 may potentially be used as an inexpensive, easily cultivatable material for the removal of lead from aqueous solution.
%K heavy metal resistant fungus
%K Penicillium sp
%K biosorption
%K isotherms
%K kinetics
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=A7CA601309F5FED03C078BCE383971DC&jid=6CB1530875F53489BF1E81BD87B7F5E6&aid=0D5043C17D1DB4E709515DD9F16BD59A&yid=140ECF96957D60B2&vid=BC12EA701C895178&iid=DF92D298D3FF1E6E&sid=AE9D5375B9B2D7F2&eid=0C7160AA184DEC96&journal_id=1001-0742&journal_name=Journalofenvironmentalsciences(China)&referenced_num=0&reference_num=28