%0 Journal Article
%T Study on gaseous CS_2 using laser-induced fluorescence
Study on gaseous CS2 using laser-induced fluorescence
%A Pan Zhe
%A Zhang Yue
%A Deng Guohong
%A Pan Xunxi
%A Hou Huiqi
%A Li Changlin
%A
Pan Zhe
%A Zhang Yue
%A Deng Guohong
%A Pan Xunxi
%A Hou Huiqi
%A Li Changlin
%J 环境科学学报(英文版)
%D 1995
%I
%X The fluorescence of gaseous CS2 was studied by laser - induced fluorescence (LIF) method. Aworking curve of gaseous CS2 was obtained and the detection limit was less than 1 ppm. The time - resolvedfluorescence emission spectrum of CS2 vapor was recorded from 350 nm to 550 nm which consists of a discretesharp band and a continuous part. The fluorescence lifetimes of the sharp band and the continuous part weremeasured to be 4 -5 and 17 microseconds respectively. The self - quenching constant (Q) of CS2 obtained is 80-150 torr-1) , and the quenching constants(Qm) of CS2 by foreign gases, CO2 , O2 , N2 , are 89. 5 , 45. 6 and30 torr-1 , respectively. All the data greatly help to understand the reactions of CS_2 in the atmosphere. Theaerosol formation in CS2 vapor after long time laser irradiation was also observed , and the mechanism of theaerosol formation was preliminarily discussed.
%K fluorescence
%K gaseous CS_2
%K LIF method
fluorescence
%K gaseous
%K CS2
%K LIF
%K method.
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=A7CA601309F5FED03C078BCE383971DC&jid=6CB1530875F53489BF1E81BD87B7F5E6&aid=65ACED59C111A21F512FCC702F798319&yid=BBCD5003575B2B5F&vid=DF92D298D3FF1E6E&iid=E158A972A605785F&sid=D8B37A0210DB6B9D&eid=D397660E39E3E461&journal_id=1001-0742&journal_name=Journalofenvironmentalsciences(China)&referenced_num=0&reference_num=0