%0 Journal Article %T Free radicals generated in photocatalytic oxidation of some organic compounds containing nitrogen atoms %A Chen Ciping %A Lu Daohui %A Xu Guangzhi %J 环境科学学报(英文版) %D 1993 %I %X Free radical intermediates generated in photocatalytic oxidation of some organic compound containing nitrogen atoms such as butylamine,piperidine,pyridine and so on were detected by spin trapping technique.The ESR spectra of N-centered radical adduct and C-centered radical adduct were observed.Experiment results reveal that these radicals are participants in the initial steps of photodegradation of these compounds. A mechanism which is consistent with the observation of these radicals species is elucidated. %K free %K radicals %K photocatalytic %K oxidation %K organic %K compounds %K ESR %K spectra %K spin %K trapping %K technique. %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=A7CA601309F5FED03C078BCE383971DC&jid=6CB1530875F53489BF1E81BD87B7F5E6&aid=97122FDC213BBE718CEFAB3DEC84B3C9&yid=D418FDC97F7C2EBA&vid=94C357A881DFC066&iid=E158A972A605785F&sid=1A033C02510EFBE6&eid=8F2250DA83AF77B8&journal_id=1001-0742&journal_name=Journalofenvironmentalsciences(China)&referenced_num=0&reference_num=0