%0 Journal Article
%T Radioactive tracer of the photochemical reaction of 14CS2 with OH in the presence of O2
%A Yang Wenxiang
%A Iyer RSRowland FS
%J 环境科学学报(英文版)
%D 1993
%I 
%X The photochemical reaction of14CS 2 with OH has been studied．The results indicated that the main products of the reaction were14COS and 14CO with a small amount of 14CO2 in the reaction system(14CS2-H2O2-C3H8-N2-O2>)．The reaction was promoted by oxygen．14COS and 14CO had the similar kinetic curves while 14CO2 got a different kind of Curve．The overall rate constant increased with the increasing of oxygen partial pressure．The rate constant for the removal of 14CS2 was K=3.4×10-12cm3/(mO1.s) at 33330 Pa 02．The conversion of 14CS2 to 14CO2 at room temperature was observed and the possible mechanism of the photochemical reaction was disscussed．
%K 14CS2
%K OH
%K photochemical
%K reaction
%K kinetics．
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=A7CA601309F5FED03C078BCE383971DC&jid=6CB1530875F53489BF1E81BD87B7F5E6&aid=E2AAF8E12D323247E1C3B1354802B77A&yid=D418FDC97F7C2EBA&vid=94C357A881DFC066&iid=E158A972A605785F&sid=30F3EEEA29E34EE7&eid=788931E6318420A3&journal_id=1001-0742&journal_name=Journalofenvironmentalsciences(China)&referenced_num=0&reference_num=0