%0 Journal Article %T Fenton treatment of 2,4-and 2,6-dinitrotoluene in soil contaminated with explosive compounds
Fenton氧化处理爆炸物污染土壤的实验研究 %A HE Yiliang %A Joseph BHughes %A Sung SooHan %A
何义亮 %A Joseph B.Hughes %A Sung SooHan %J 环境科学学报 %D 2007 %I %X The performance and technical parameters of Fenton treatment of 2,4-and 2,6-dinitrotoluene(DNT)in soil contaminated with explosive compounds has been investigated at laboratory scale.The experimental results showed that 2,4-and 2,6-DNT were removed completely in two hours while 87% of COD was removed in eight hours.The optimal H2O2 concentration was 26.46mmol,corresponding to a FeSO4:H2O2 mole ratio of 1:36.78~73.56.Much better removal performance can be achieved by Fenton oxidation treatment of washing-out liquid than by direct oxidation of contaminated soil on a column.Based on kinetic analysis and acetone inhibition assays,it was concluded that Fenton oxidation of 2,4-DNT is easier than oxidation of 2,6-DNT.GC-MS analysis showed that not only 2,4-DNT and 2,6-DNT but also other nitroaromatic organic compounds were totally removed during Fenton oxidation treatment. %K Fenton oxidation %K explosives contaminated soil %K 2 %K 4-DNT %K 2 %K 6-DNT
Fenton氧化 %K 爆炸物污染土壤 %K 2 %K 4-DNT %K 2 %K 6-DNT %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=A7CA601309F5FED03C078BCE383971DC&jid=03A55E61A8750ACAC6AF81EF9E2AC838&aid=815415A8B6CEB926B252280870F14DFE&yid=A732AF04DDA03BB3&vid=DB817633AA4F79B9&iid=F3090AE9B60B7ED1&sid=C48302AEE9AFB6AE&eid=3DE6111EA92D7986&journal_id=0253-2468&journal_name=环境科学学报&referenced_num=0&reference_num=11