%0 Journal Article
%T Honeycomb-like ceramic used for catalytic ozonation of acetophenone in water<br>蜂窝陶瓷催化臭氧化苯乙酮的研究
%A LIU Pengpeng
%A ZHANG Hu
%A SHI Rui
%A TONG Shaoping
%A MA Chun''an
%A <br>刘朋朋
%A 张华
%A 石锐
%A 童少平
%A 马淳安
%J 环境科学学报
%D 2010
%I 
%X The effect of honeycomb-like ceramic on the efficiency of ozonation of acetophenone in water was investigated. The results showed that the presence of honeycomb-like ceramic significantly improved the efficiency of ozonation of acetophenone, and that this catalytic ozonation system followed the mechanism of  OH oxidation by a test of adding tert-butanol. The kinetics of honeycomb-like ceramic-catalytic ozonation of acetophenone could be divided into two stages. The values of apparent reaction rate constant and Rct were 8.77×10-4 s-1 and 10.34×10-10 for the first stage; and 4.63×10-3 s-1 and 172.34×10-10 for the second stage, respectively. Basing on the change of water color, analysis of sample by atomic absorption spectrometry, and the kinetic of degradation, we speculated that Ti4+ leaching from honeycomb-like ceramic was the main factor for the improvement of degradation rate of acetophenone.
%K acetophenone
%K catalytic ozonation
%K honeycomb-like ceramic
%K hydroxyl radical
%K degradation<br>苯乙酮
%K 催化臭氧
%K 蜂窝陶瓷
%K 羟基自由基
%K 降解
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=A7CA601309F5FED03C078BCE383971DC&jid=03A55E61A8750ACAC6AF81EF9E2AC838&aid=82BFFE0CEA8A58445CEE536AE49B7AB6&yid=140ECF96957D60B2&vid=340AC2BF8E7AB4FD&iid=F3090AE9B60B7ED1&sid=CD65D483B6C24C75&eid=716EB46D8C8238F5&journal_id=0253-2468&journal_name=环境科学学报&referenced_num=0&reference_num=0