%0 Journal Article %T APPLICATION OF MASS-ACTION MODEL FOR DESCRIBING THE ABSORPTION CHARACTERISTICS OF HEAVY METALS ON SOILS
用质量作用模型描述重金属离子在土壤中的吸附特点 %A Zhou daihu %A Li Xueyuan %A Xu Fenglin %A Dong Yuanyan %A
周代华 %A 李学垣 %A 徐凤琳 %A 董元彦 %J 环境科学学报 %D 1996 %I %X A mass-action model used to describe adsorption at the solid/solution interface was derived from the surface chemical reaction and equilibrium principles:The model has the characteristics of both langmiur and Freundlich equations. Ka is equilibrium constant of adsorption reaction and could be regarded as the intensive index of the adsorption; n indicates the number of adsorbed molecules or ions covering each active site on the surface , it is helpful to decide the mechanism of reaction; M is refereed to as the sum total of active sites on the surface of adsorbent; the adsorption capacity is determined by both M and n concurrently.The model was applied to the adsorption of Cu and Zn on red soil,Yellow-brown soil and grey chao soil. %K adsorption %K heavy metals %K mass-action model %K soils
土壤 %K 吸附 %K 重金属 %K 质量作用模型 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=A7CA601309F5FED03C078BCE383971DC&jid=03A55E61A8750ACAC6AF81EF9E2AC838&aid=15818206CBE696C2168F127EB09858DA&yid=8A15F8B0AA0E5323&vid=7801E6FC5AE9020C&iid=E158A972A605785F&sid=F10601728A1E9BEA&eid=389DA78D878702A9&journal_id=0253-2468&journal_name=环境科学学报&referenced_num=13&reference_num=12