%0 Journal Article %T PHOTOCATALYTIC OXIDATION OF PHENOL ON TiO2 PRATICLE 1.PRODUCTS DISTRIBUTIO ON AND PEACTION PATHWAY
在TiO2催化剂上苯酚光催化氧化反应研究1.降解产物分布及反应途径 %A Wang Yizhong %A Hu Chun %A Tong Hongxiao %A
王怡中 %A 胡春 %A 汤鸿霄 %J 环境科学学报 %D 1995 %I %X The photocatalytic oxidation of phenol in TiO_2 particle suspensions has been studied in atest reactor illuminated with a 5000 W medium pressure mercury lamp.Eight main productshave been identified by HPLC, IC,TOC and GC /MS.The results indicated that there arethree stages of reaction from the viewpoint of products distribution, there are hydroxyla-tion,carboxylation and mineralization,The oxidation process could be explained nd justifiedby means of coricentration variation of main products like pyrocatechol,fumaric acid andCO_2 and the carbon mass balance achieved 94.4%,The effects of CO_2 concentration in gas phase on the phenol decomposition and products distribution have been investigation. %K photocatalytic oxidation %K phenol %K products distribution
光催化 %K 氧化 %K 苯酚 %K 降解产物 %K 水处理 %K TiO2催化剂 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=A7CA601309F5FED03C078BCE383971DC&jid=03A55E61A8750ACAC6AF81EF9E2AC838&aid=565942E7D3038E5E309A9F9D92295562&yid=BBCD5003575B2B5F&vid=23CCDDCD68FFCC2F&iid=E158A972A605785F&sid=7D1E6EEC2019967D&eid=A33A8FD1432A4C3E&journal_id=0253-2468&journal_name=环境科学学报&referenced_num=51&reference_num=1