%0 Journal Article %T Studies on photodegradation of carbendazim in solvents and aqueous solutions
多菌灵的光化学降解研究 %A XU Baocai %A YUE Yongde %A HU Yinghui %A HUA Rimao %A
徐宝才 %A 岳永德 %A 胡颍蕙 %A 花日茂 %J 环境科学学报 %D 2000 %I %X Under sunlight or high pressure mercury lamp(HPML),the phototransformation of carbendazim in solvents and aqueous solutions was studied.The main results were summarized as follows:Carbendazim decomposed very slowly in aqueous phase, n \|hexane and methanol under sunlight.The photolytic rate of MBC in acetone was high with half\|life of 33.80?h.Photosensitizer such as riboflavin,0 5% acetone and Fe 3 ,can enhance photolysis of MBC in aqueous solutions.Among them,riboflavin is the most senstivive one MBC can be degraded by 53 47% after 16 hours.Three pesticides,namely,triadimefon,butachlor,and carbofuran can affected significantly the photodecomposition of MBC in water under HPML.By 2 hours irradiation,the photoquench efficiency of triadimefon,butachlor and carbofuran on cabendazim are 244 05%,252 81%,and 262 92%,respectively.Under HPML,direct photolysis is the main process.The half\|life in redistilled water is 74 62?min.The photolytic rates of carbendazim in different water types or pH show following sequence:redistilled water>river water>pond water,or,pH4>pH9>pH7. %K carbendazim %K phototransformation %K photosensitizer %K organic solvents aqueous solutions
多菌灵 %K 光解 %K 有机溶剂 %K 杀菌剂 %K 农药 %K 废水处理 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=A7CA601309F5FED03C078BCE383971DC&jid=03A55E61A8750ACAC6AF81EF9E2AC838&aid=814B17F328B241FD&yid=9806D0D4EAA9BED3&vid=A04140E723CB732E&iid=94C357A881DFC066&sid=984BD2F4D19B9D1C&eid=E6A0A363CA4FC5CF&journal_id=0253-2468&journal_name=环境科学学报&referenced_num=22&reference_num=3