%0 Journal Article
%T KINETICS OF DEEP OXIDATION OF BUTANE, TRANS-BUTENE-2 AND CIS-BUTENE-2 ON Pt/AI203 CATALYST<br>在Pt/Al2O3催化剂上丁烷、反-丁烯-2及顺-丁烯-2深度氧化动力学
%A Hu Keyuan
%A Jin Yun
%A Zhang Ruiqin
%A <br>俞启全
%A 金韵
%A 张瑞芹
%J 环境科学学报
%D 1988
%I 
%X The kinetics of deep oxidation of butane,trans-butene and cis-butene-2 on Pt/Al2O3 catalyst has been investigated by a flow-recirculatiqn glass reactor. The kinetics of the reactions was found to obey the L-H model. The parameter values of the kinetic equation were estimated by the method of orthogonal design. A pulse method was used to discriminate the L-H model and to determine the adsorption heats of butane, trans-butene-2,cis-butene-2 and oxygen. The rate of CO2 formation during the oxidation might be described by the equations (11).
%K butane
%K trans-butene-2
%K cis-butene-2
%K catalyst
%K deep oxidation
%K L-H model<br>丁烷
%K 反-丁烯-2
%K 顺-丁烯-2
%K Pt/Al_2O_3催化剂
%K 深度氧化
%K 动力学
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=A7CA601309F5FED03C078BCE383971DC&jid=03A55E61A8750ACAC6AF81EF9E2AC838&aid=AFBB578A7D2D80833D56942DFCA3A6FC&yid=0702FE8EC3581E51&vid=5D311CA918CA9A03&iid=CA4FD0336C81A37A&sid=D767283A3B658885&eid=EDA22B444205D04A&journal_id=0253-2468&journal_name=环境科学学报&referenced_num=0&reference_num=0